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Magnetic isotope effects in biradicals: Substantial 13C enrichment and a novel mechanistic probe
Nicholas J. Turro (Columbia University), Charles E. Doubleday (Columbia University), Kuo‐Chu Hwang (Columbia University), Chen Chih Cheng (Columbia University), James R. Fehlner (Pennsylvania State University, Columbia University)
Tetrahedron Letters
DOI: 10.1016/s0040-4039(00)96246-4 (Chemistry)
Licence : CC BY-NC-ND
Résumé : Photolysis of 2,n-diphenylcycloalkanones (n-membered ring, n = 10, 11, 12, 15) produces products that are significantly enriched in 13C. The enrichments are different for each product, and this allows assignment of the dynamic pathways through which each product is formed.
Publié le 01 Jan. 1987